Methyllithium is the simplest organolithium reagent, with the empirical formula CH 3 Li. This s-block organometallic compound adopts an oligomeric structure both in solution and in the solid state.

2025年2月1日 · Lithium, methyl- | CH3Li | CID 2724049 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.

Methyllithium is an organolithium reagent mainly used for deprotonation and as a source of methyl anion. It is a strong base and a strong nucleophile. [1] Methyllithium solution (1.6M in diethyl ether) has been used for the asymmetric allylic alkylation (AAA) of allylic electrophiles in the presence of a chiral copper catalyst.

2011年4月22日 · Methyllithium is a strong base and nucleophile that can be prepared by reacting methyl bromide or methyl chloride with lithium in diethyl ether. It is commonly used for deprotonations and as a source of methyl anion in various chemical reactions.

Methyllithium is the simplest organolithium reagent, with the empirical formula CH 3 Li. This s-block organometallic compound adopts an oligomeric structure both in solution and in the solid state.

Methyllithium is an organolithium reagent with the empirical formula CH 3 Li. This s-block organometallic compound adopts an oligomeric structure both in solution and in the solid state. This highly reactive compound, invariably used as a solution in alkanes or ethers, is a reagent in organic synthesis as well as organometallic chemistry.

2025年1月27日 · There are no significant industrial uses of methyllithium, but it is widely used in the laboratory in Grignard type reactions. Methyllithium is an organolithium reagent mainly used for deprotonation and as a source of methyl anion. It is a strong base and a strong nucleophile.

Methyllithium is an organolithium compound with the formula CH3Li, where a lithium atom is bonded to a methyl group. This compound is a highly reactive reagent commonly used in organic synthesis to form carbon-carbon bonds, making it valuable …

Organometallic compounds such as methyllithium (CH 3 Li) constitute one type of anionic initiator. The methyl group of this initiator adds to the styrene monomer to form the anionic species that is associated with the lithium ion Li +:

Methyllithium is both strongly basic and highly nucleophilic due to the partial negative charge on carbon and is therefore particularly reactive towards electron and proton donors. THF, usually a chemically inert solvent, is attacked by MeLi. Water and alcohols react violently.